Preparations of Haloalkanes

IMPORTANT

Preparations of Haloalkanes: Overview

This topic covers concepts, such as Preparations of Haloalkanes, Preparation of Haloalkanes From Alcohols, Preparation of Haloalkanes by Free Radical Halogenation of Alkanes, and Preparation of Haloalkanes by Addition of Halogen Acids to Alkenes.

Important Questions on Preparations of Haloalkanes

EASY
IMPORTANT

 The major product of the following reaction is: CH3CH2CH=CH2+HBr

EASY
IMPORTANT

Which of the following is an example of Sandmeyer reaction:

(i)

 C6H5N2+Cl-       +         KI   C6H5I + KCl + N2Benzene diazonium chloride   Iodobenzene

 (ii)

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In the presence of peroxide, hydrogen chloride and hydrogen iodide do not give anti-Markovnikoff’s addition with alkenes, because of the fact that:

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Consider the following reaction

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Identify the structure of the major product X.

EASY
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The reaction condition leading to the best yield of   C2H5Cl are –

MEDIUM
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The reaction condition leading to the best yield of C 2 H 5 Cl are

EASY
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The following reaction is known as
R-CH2Br+AgF ethyleneglycol ΔR-CH2 F+AgBr

HARD
IMPORTANT

Which of the following cannot be prepared by Sandmeyer's reaction?

MEDIUM
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Which of the following will not give haloderivative by addition of HBr?

EASY
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Chlorobenzene is prepared commercially by

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Chlorobenzene is formed by reaction of chlorine with benzene in the presence of AlCl3. Which of the following species attacks the benzene ring in this reaction?

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Which of the following alcohols will yield the corresponding alkyl chloride on reaction with concentrated HCl at room temperature?

EASY
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The reaction, RCl+NaIAcetoneRI+NaCl, is known as

MEDIUM
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The reaction of toluene with chlorine in the presence of iron and in the absence of light yields _____.

HARD
IMPORTANT

What happens in Finkelstein reactions?

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For the chemical reaction:
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The IUPAC name of the product is:

MEDIUM
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Conversion of methyl chloride into methyl fluoride is known as

MEDIUM
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What are X, Y and Z in the following reaction:

R-OH+PCl5X+Y+Z

HARD
IMPORTANT

Which one of the following hydrocarbons when treated with chlorine will give only, single monochloro compound?

EASY
IMPORTANT

Which of the following substrate is most reactive toward free radical substitution reaction :-